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Oxides of nitrogen (NOx) are air pollutants that cause chemiluminescent
smog. Rotary kilns emit relatively high levels of thermal NOx and kiln
operators are under increasing pressure to reduce NOx, even though their
contribution to the overall level in the atmosphere is small. Hence kiln
operators have to meet ever more stringent emissions regulations.
NOx forms by oxidation of the nitrogen in the air and from the organic
nitrogen compounds in the fuel. Three formation mechanisms exist; Thermal
NOx, Fuel NOx and Prompt NOx. Since thermal NOx is the dominant mechanism
of NOx formation in kiln flames, NOx reduction techniques commonly adopted
concentrate on reducing both flame temperature and oxygen in the flame
by simply reducing the fuel/air mixing rates. Although this can be effective
at reducing NOx it can also substantially reduce the heat transfer to
the product, resulting in reduced production rates and/or poor
product quality.
NOx usually is formed in the high temperature zone close to the burner
nozzle. A good knowledge of the aerodynamics is used by FCT to ensure
reduced oxygen concentrations and temperatures in this region whilst maintaining
the overall fuel/air mixing and heat transfer rates. Thus NOx is minimised
but production rates and product quality maintained.
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